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  • Construction of Multiple Nonpolar SF6 Nano‐Traps by Highly Stable . . .
    Herein, a novel strategy is introduced to construct unique pore channels with multiple SF 6 nano-traps by precisely selecting bipyrazole ligands to design the nonpolar surface of microporous metal−organic frameworks (MOFs), which significantly enhances the material's affinity for SF 6
  • 【Co (BPZ)】基于高稳定性吡唑基金属有机框架构建多个非 . . .
    华南理工大学夏启斌团队在本文中（Small 2025, 2409215）介绍了一种新颖策略，通过精确选择双吡唑配体设计微孔金属有机框架（MOFs）的非极性表面，构建出带有多个纳米陷阱的独特孔道，显著增强了材料对的亲和力。 合成并研究了一系列超稳定的双吡唑基金属有机框架（ZnBPZ、CoBPZ、NiBPZ ）。 在这三种材料中，和在 298K、0 1bar 下对的吸附量分别达到 2 47 和 2 39 ，对 （10 90，体积比）的 IAST 选择性高达 748。 穿透实验表明，能高效分离 混合物，（≥99 5%）的产率可达 46 1 。 理论计算显示，更倾向于通过多个（吡唑环）范德华相互作用吸附在孔道中。 该研究为探索高效 分离的吸附剂提供了直接方法。
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    微信扫码关注登录 登录即代表同意 《X-MOL隐私策略》 —————其它方式登录—————
  • N-Type Self-Assembled Monolayers (SAMs): The Next Star Materials in the . . .
    Self-assembled monolayers (SAMs) play a critical role in modifying the buried interface of perovskite solar cells (PVSCs) by modulating the crystallization dynamics of perovskites and adjusting energy level alignment between perovskite layer and electrode
  • Nitrogen‐Doped Hard Carbon Anode from Redwood Biomass . . .
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  • Bamboo‐Inspired Hierarchically Hollow Aerogel MXene Fibers with . . .
    Hollow and porous MXene aerogel fiber material (HA-Ti3C2TX fiber) is proposed for energy storage and conversion The HA-Ti3C2TX fiber possesses fast ion charge diffusion kinetics to charge storage an
  • pH Modulated Atomic Distribution in NiMo Alloys for Ultrastable Water . . .
    NiMo alloys are highly promising catalysts for the alkaline hydrogen evolution reaction (HER) By employing a pH-modulated “hereditary engineering” strategy, we achieved controlled three-dimensional
  • pH-Adaptive Microneedle Patch Based on Cerium-Based Prussian Blue . . .
    The presence of biofilm formation, excessive inflammatory responses, and a dynamic microenvironment makes methicillin-resistant Staphylococcus aureus (MRSA)-associated chronic wound infections difficult to cure To address this challenge, we developed a smart pH-responsive hyaluronic acid microneedle patch (CV MN) loaded with vancomycin and cerium-based Prussian blue analogs (CPB) for time
  • Fluorine‐Doping Carbon‐Modified Si SiOx to Effectively Achieve High . . .
    To address the significant challenges encountered by silicon-based anodes in high-performance lithium-ion batteries (LIBs), including poor cycling stability, low initial coulombic efficiency (ICE), and insufficient interface compatibility, this work innovatively prepares high-performance Si SiOx@F-C composites via in situ coating fluorine-doping





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